NEET • Chemistry

General Organic Chemistry

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Inductive Effect

The source defines inductive effect as permanent displacement of sigma-bond pair electrons due to a dipole or polar bond.

inductive effect
C4C3C2C1Clδδδ+δδ+δ+δ-electron withdrawal by -Cl through σ bonds

Notes

  • It is also called transmission effect.

  • It causes permanent polarisation in the molecule.

  • Electrons never leave their original atomic orbital.

  • Its magnitude decreases with distance and is almost negligible after the third carbon atom.

  • It operates through sigma bonds and does not involve pi-bond electrons.