comparisonKMnO4 / Dichromate Oxidation MapThe source begins oxidation with KMnO4 in both media or K2Cr2O7 in acidic medium.SubstrateProduct shownAldehydeacid1∘1^\circ1∘ alcoholacid2∘2^\circ2∘ alcoholketone3∘3^\circ3∘ alcoholno reactionalkeneR2C=O+R′COOHR_2C=O+R'COOHR2C=O+R′COOHR−C≡C−R′R-C{\equiv}C-R'R−C≡C−R′RCOOH+R′COOHRCOOH+R'COOHRCOOH+R′COOHaromatic side chainbenzoic acid side-chain productoxidation ladder1° alcoholaldehydeacid2° alcoholketonestrong oxidants reach acid3° alcohol: no reaction in listed oxidationsNotesOxidant: KMnO4KMnO_4KMnO4 in both medium or K2Cr2O7K_2Cr_2O_7K2Cr2O7 in acidic medium.