JEE • Chemistry

s-Block Elements & their compounds

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table

Group 1, Group 2 and Hydration

The s-block section opens with group membership and hydration trends.

Members
GroupElements listed

Group 1

Li, Na, K, Rb, Cs and Fr

Group 2

Be, Mg, Ca, Sr, Ba and Ra

Hydration
IonsSource-backed trend

Alkali metal ions

Hydration enthalpies decrease with increase in ionic size; Li+Li^+ has maximum hydration.

Alkaline earth metal ions

Be2+>Mg2+>Ca2+>Sr2+>Ba2+Be^{2+}>Mg^{2+}>Ca^{2+}>Sr^{2+}>Ba^{2+}.

Group comparison

Alkaline earth metal ion hydration enthalpies are larger than alkali metal ion hydration enthalpies.

Notes

  • Lithium salts are mostly hydrated; the source example is LiCl⋅2H2OLiCl\cdot 2H_2O.